New Chiral Ferrocene‐Bridged Phosphole–Phosphane Ligands | Zendy

Guadalupe Lopez Cortes Jose | Zendy; Ramon Olivier | Zendy; Vincendeau Sandrine | Zendy; Serra Daniel | Zendy; Lamy Franck | Zendy; Daran JeanClaude | Zendy; Manoury Eric | Zendy; Gouygou Maryse | Zendy

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New Chiral Ferrocene‐Bridged Phosphole–Phosphane Ligands

Author(s) -

Guadalupe Lopez Cortes Jose,

Ramon Olivier,

Vincendeau Sandrine,

Serra Daniel,

Lamy Franck,

Daran JeanClaude,

Manoury Eric,

Gouygou Maryse

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600771

Subject(s) - phosphole , chemistry , palladium , allylic rearrangement , ferrocene , substitution reaction , stereochemistry , enantioselective synthesis , catalysis , combinatorial chemistry , medicinal chemistry , organic chemistry , electrochemistry , electrode

A convenient synthesis of new chiral ferrocenene‐bridged phosphole–phosphane ligands in an enantiomerically pure form has been developed. These new chiral P,P ligands have been tested in a palladium‐catalysed allylic substitution reaction. High activities and moderate enantioselectivities (up to 61 %) were observed. A palladium(II) complex has been isolated and its crystal structure established. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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