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Adducts of Cp 3 Ln with LGa(Me)OH, Syntheses and X‐ray Crystal Structures of LGa(Me)HO→LnCp 3 {Ln = Sm, Nd, Yb; L = HC[C(Me)N(2,6‐ i Pr 2 C 6 H 3 )] 2 }
Author(s) -
Singh Sanjay,
Pal Aritra,
Roesky Herbert W.,
HerbstIrmer Regine
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600650
Subject(s) - chemistry , adduct , lanthanide , crystal structure , gallium , crystallography , x ray , elemental analysis , stereochemistry , inorganic chemistry , organic chemistry , ion , physics , quantum mechanics
Various heterodimetallic (gallium‐lanthanide) compounds have been prepared by the reaction of LGa(Me)OH ( 2 ) with Cp 3 Ln. Thus, the adducts LGa(Me)HO→LnCp 3 (Ln = Sm, 3 ; Nd, 4 ; Yb, 5 ) were obtained and characterized by IR spectroscopy and elemental analyses. The single‐crystal X‐ray structures of 3 and 4 are also reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)