ZnO Nanoparticles From a Metal‐Organic Framework Containing Zn II  Metallacycles | Zendy

Thakuria Harjyoti | Zendy; Borah Ballav Moni | Zendy; Das Gopal | Zendy

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ZnO Nanoparticles From a Metal‐Organic Framework Containing Zn II Metallacycles

Author(s) -

Thakuria Harjyoti,

Borah Ballav Moni,

Das Gopal

Publication year - 2007

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600623

Subject(s) - chemistry , nitrilotriacetic acid , wurtzite crystal structure , hydroxide , zinc , nanoparticle , metal organic framework , zinc hydroxide , decomposition , metal , inorganic chemistry , phase (matter) , polymer chemistry , nuclear chemistry , chemical engineering , organic chemistry , chelation , adsorption , engineering

Nitrilotriacetic acid (H 3 NTA) reacts in the solid phase with zinc hydroxide (1:1) to form a 3D ladder‐like metal‐organic framework that forms wurtzite ZnO nanoparticles when heated above 600 °C. Complex 1 contains a 1D zig‐zag water chain. A mixed coordination network 2 is formed with excess Zn II hydroxide, which, on decomposition at about 500 °C, forms microwires of ZnO.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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