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Alk‐2‐ynyl Trimethylsilyl Chalcogenoethers by Nucleophilic Substitution of Propargyl Bromides
Author(s) -
Taher Deeb,
Wallbank Andrew I.,
Turner Elizabeth A.,
Cuthbert Heather L.,
Corrigan John F.
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600583
Subject(s) - chemistry , propargyl , trimethylsilyl , thermal decomposition , yield (engineering) , lithium (medication) , nucleophile , nucleophilic substitution , medicinal chemistry , organic chemistry , catalysis , medicine , materials science , metallurgy , endocrinology
Lithium (trimethylsilyl)chalcogenolates have been generated and used to prepare a series of alk‐2‐ynyl trimethylsilyl chalcogenoethers from the corresponding propargyl bromides in good yield. The thermal decomposition of the telluroethers has also been studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)