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A Novel Copper(I) Halide Framework Templated by Organic–Inorganic Hybrid Polyoxometalate Chains Formed In Situ: A New Route for the Design and Synthesis of Porous Frameworks
Author(s) -
Jin Hua,
Qi Yanfei,
Wang Enbo,
Li Yangguang,
Qin Chao,
Wang Xinlong,
Chang Song
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600558
Subject(s) - polyoxometalate , chemistry , halide , hybrid material , copper , metal organic framework , inorganic chemistry , chloride , polymer chemistry , crystallography , catalysis , organic chemistry , adsorption
A 1D organic–inorganic hybrid polyoxometalate chain has been used as a non‐coordinating anionic template for the construction of a novel 3D copper halide 4,4′‐bipy framework, namely [Cu 3 I Cl(4,4′‐bipy) 4 ][Cu II (1,10‐phen) 2 Mo 8 O 26 ]. X‐ray diffraction experiments revealed that the title compound consists of chloride‐bridged trinuclear Cu I units linked by neutral organic 4,4′‐bipy groups into a 3D framework with hexagon‐like channels in which 1D organic–inorganic hybrid polyoxometalate chains reside. This is the first example of a 1D organic–inorganic hybrid polyoxometalate chain functioning as a novel anionic template for the construction of a 3D framework. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)