Synthesis of a BEDT‐TTF Bipyridine Organic Donor and the First Fe II  Coordination Complex with a Redox‐Active Ligand | Zendy

Hervé Katel | Zendy; Liu ShiXia | Zendy; Cador Olivier | Zendy; Golhen Stéphane | Zendy; Le Gal Yann | Zendy; Bousseksou Azzedine | Zendy; StoeckliEvans Helen | Zendy; Decurtins Silvio | Zendy; Ouahab Lahcène | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of a BEDT‐TTF Bipyridine Organic Donor and the First Fe II Coordination Complex with a Redox‐Active Ligand

Author(s) -

Hervé Katel,

Liu ShiXia,

Cador Olivier,

Golhen Stéphane,

Le Gal Yann,

Bousseksou Azzedine,

StoeckliEvans Helen,

Decurtins Silvio,

Ouahab Lahcène

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600351

Subject(s) - chemistry , tetrathiafulvalene , redox , ligand (biochemistry) , coordination complex , mössbauer spectroscopy , bipyridine , crystallography , stereochemistry , inorganic chemistry , crystal structure , metal , molecule , organic chemistry , biochemistry , receptor

The synthesis of the new ligand, BEDT‐TTF‐bipy [4,5‐ethylenedithio‐4′,5′‐(4′‐methyl‐2,2′‐dipyrid‐4‐ylethylenedithio)tetrathiafulvalene] is reported. The first Fe II coordination complex, namely [Fe(NCS) 2 (BEDT‐TTF‐bipy) 2 ] · CHCl 3 , with this redox‐active ligand is obtained. Magnetic measurements and Mössbauer spectroscopy revealed the coexistence of high‐spin and low‐spin Fe II species with a ratio of 40:60 in this compound. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research