Synthesis, Structures, and Luminescent Properties of d 10  Group 12 Metal Complexes with Substituted 2,2′‐Bipyridine Ligands | Zendy

Liu Xiaoming | Zendy; Mu Xiaoyue | Zendy; Xia Hong | Zendy; Ye Ling | Zendy; Gao Wei | Zendy; Wang Haoyu | Zendy; Mu Ying | Zendy

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Synthesis, Structures, and Luminescent Properties of d 10 Group 12 Metal Complexes with Substituted 2,2′‐Bipyridine Ligands

Author(s) -

Liu Xiaoming,

Mu Xiaoyue,

Xia Hong,

Ye Ling,

Gao Wei,

Wang Haoyu,

Mu Ying

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600262

Subject(s) - chemistry , luminescence , trigonal bipyramidal molecular geometry , crystallography , metal , crystal structure , group (periodic table) , tetrahedral molecular geometry , trigonal pyramidal molecular geometry , coordination geometry , mercury (programming language) , stereochemistry , molecule , organic chemistry , hydrogen bond , physics , optoelectronics , computer science , programming language

Four d 10 group 12 metal complexes, 6‐(2‐methoxyphenyl)‐2,2′‐bipyridinezinc dichloride ( 2a ), ‐mercury dichloride ( 2b ), 6‐[2‐(dimethylamino)phenyl]‐2,2′‐bipyridinezinc dichloride ( 2c ), and ‐mercury dichloride ( 2d ), were synthesized and the structures determined by single‐crystal X‐ray crystallography. Complexes 2a and 2b are four‐coordinate and adopt a distorted tetrahedral geometry, while complexes 2c and 2d are five‐coordinate with a distorted trigonal bipyramidal geometry for the metal center. Luminescent properties of complexes 2a – 2d in both solution and the solid state were studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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