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Synthesis, Structures, and Luminescent Properties of d 10 Group 12 Metal Complexes with Substituted 2,2′‐Bipyridine Ligands
Author(s) -
Liu Xiaoming,
Mu Xiaoyue,
Xia Hong,
Ye Ling,
Gao Wei,
Wang Haoyu,
Mu Ying
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600262
Subject(s) - chemistry , luminescence , trigonal bipyramidal molecular geometry , crystallography , metal , crystal structure , group (periodic table) , tetrahedral molecular geometry , trigonal pyramidal molecular geometry , coordination geometry , mercury (programming language) , stereochemistry , molecule , organic chemistry , hydrogen bond , physics , optoelectronics , computer science , programming language
Four d 10 group 12 metal complexes, 6‐(2‐methoxyphenyl)‐2,2′‐bipyridinezinc dichloride ( 2a ), ‐mercury dichloride ( 2b ), 6‐[2‐(dimethylamino)phenyl]‐2,2′‐bipyridinezinc dichloride ( 2c ), and ‐mercury dichloride ( 2d ), were synthesized and the structures determined by single‐crystal X‐ray crystallography. Complexes 2a and 2b are four‐coordinate and adopt a distorted tetrahedral geometry, while complexes 2c and 2d are five‐coordinate with a distorted trigonal bipyramidal geometry for the metal center. Luminescent properties of complexes 2a – 2d in both solution and the solid state were studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)