Dithiolato‐Bridged [MRu 2 ] (M = Rh, Ir, Ru) Triangular 50e –  Cluster Complexes Synthesized by Complete Metal Framework Reconstruction | Zendy

Nakagawa Norikiyo | Zendy; Murata Masaki | Zendy; Sugimoto Manabu | Zendy; Nishihara Hiroshi | Zendy

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Dithiolato‐Bridged [MRu 2 ] (M = Rh, Ir, Ru) Triangular 50e – Cluster Complexes Synthesized by Complete Metal Framework Reconstruction

Author(s) -

Nakagawa Norikiyo,

Murata Masaki,

Sugimoto Manabu,

Nishihara Hiroshi

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600255

Subject(s) - chemistry , crystallography , cluster (spacecraft) , metal , x ray crystallography , electron counting , transition metal , diffraction , electron , catalysis , physics , organic chemistry , computer science , optics , programming language , biochemistry , quantum mechanics

A method for synthesizing triangular dithiolene‐bridged trinuclear cluster complexes [{LM(S 2 C 6 H 4 )}Ru 2 (CO) 4 (S 2 C 6 H 4 )] [M = Rh, L = (η 5 ‐C 5 Me 5 ); M = Ir, L = (η 5 ‐C 5 Me 5 ); M = Ru, L = (η 6 ‐C 6 Me 6 )] by complete reconstruction of the metal framework was developed. The complexes thus obtained have 50 electrons around the metal atoms, indicating 3c4e – bonds; their molecular structures were determined by X‐ray diffraction analyses and theoretical calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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