First Example of Dendrons as Topological Amplifiers | Zendy

Turrin CédricOlivier | Zendy; Maraval Alexandrine | Zendy; Magro Germinal | Zendy; Maraval Valérie | Zendy; Caminade AnneMarie | Zendy; Majoral JeanPierre | Zendy

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First Example of Dendrons as Topological Amplifiers

Author(s) -

Turrin CédricOlivier,

Maraval Alexandrine,

Magro Germinal,

Maraval Valérie,

Caminade AnneMarie,

Majoral JeanPierre

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600217

Subject(s) - chemistry , dendrimer , phosphorus , nuclear magnetic resonance spectroscopy , spectroscopy , crystallography , stereochemistry , topology (electrical circuits) , polymer chemistry , organic chemistry , physics , mathematics , quantum mechanics , combinatorics

A phosphorus‐containing dendron was synthesized and grafted to a tetraphosphorus macrocycle. The presence of such bulky substituents allowed for the first time the amplification of topological differences in the macrocycle. These differences become detectable by 31 P NMR spectroscopy, with the appearance of several signals for the phosphorus atoms included in the macrocycle. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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