Synthesis and Structural Characterization of a Halide‐Free Rhombohedral Silver‐Alkynyl Cage Complex [Ag 14 (C 2  t Bu) 12 ][BF 4 ] 2 | Zendy

AbuSalah Omar M. | Zendy; Ja’far Mohammed H. | Zendy; AlOhaly Abdel Razzak | Zendy; AlFarhan Khalid A. | Zendy; AlEnzi Hamda S. | Zendy; Dolomanov Oleg V. | Zendy; Howard Judith A. K. | Zendy

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Synthesis and Structural Characterization of a Halide‐Free Rhombohedral Silver‐Alkynyl Cage Complex [Ag 14 (C 2 t Bu) 12 ][BF 4 ] 2

Author(s) -

AbuSalah Omar M.,

Ja’far Mohammed H.,

AlOhaly Abdel Razzak,

AlFarhan Khalid A.,

AlEnzi Hamda S.,

Dolomanov Oleg V.,

Howard Judith A. K.

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600128

Subject(s) - chemistry , halide , cationic polymerization , acetone , crystal structure , crystallography , stereochemistry , trigonal crystal system , medicinal chemistry , x ray crystallography , polymer chemistry , inorganic chemistry , organic chemistry , diffraction , physics , optics

The novel cationic complex [Ag 14 (C 2 t Bu) 12 ] 2+ has been synthesized by four reactions: reaction of [Ag(C 2 t Bu)] n and AgBF 4 in acetone in a 6:1 mole ratio, that of HC≡C t Bu and AgBF 4 in water in the absence of a base, treatment of [AgC 2 t Bu] n with HBF 4 in acetone or that of {[Ag 3 (C 2 t Bu) 2 ][BF 4 ]} n with [Ag(C 2 t Bu)] n in a 1:4 mole ratio. Single‐crystal X‐ray studies showed it to be a hexacapped cube of silver( I ) atoms, with twelve η 1 , μ 3 ‐C 2 t Bu ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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