Synthesis and Molecular Structure of [Cp*Ta(Ph)(P 6 Ph 5 )]: A Terminal Phosphinidene Complex of the (P 6 Ph 5 ) 3–  Ligand (Cp* = C 5 Me 5 ) | Zendy

Wolf Robert | Zendy; HeyHawkins Evamarie | Zendy

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Synthesis and Molecular Structure of [Cp*Ta(Ph)(P 6 Ph 5 )]: A Terminal Phosphinidene Complex of the (P 6 Ph 5 ) 3– Ligand (Cp* = C 5 Me 5 )

Author(s) -

Wolf Robert,

HeyHawkins Evamarie

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200600084

Subject(s) - phosphinidene , chemistry , yield (engineering) , ligand (biochemistry) , nuclear magnetic resonance spectroscopy , stereochemistry , crystallography , inorganic chemistry , biochemistry , materials science , receptor , metallurgy

The terminal phosphanyl phosphinidene complex [Cp*Ta(Ph)(P 6 Ph 5 )] ( 2 ) has been isolated in 16 % yield from the reaction of [Cp*TaCl 4 ] with 2 equiv. Na 2 (P 4 Ph 4 ) and displays an η 4 ‐bound (P 6 Ph 5 ) 3– ligand according to X‐ray crystallography and 31 P NMR spectroscopy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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