Premium
Synthesis and Molecular Structure of [Cp*Ta(Ph)(P 6 Ph 5 )]: A Terminal Phosphinidene Complex of the (P 6 Ph 5 ) 3– Ligand (Cp* = C 5 Me 5 )
Author(s) -
Wolf Robert,
HeyHawkins Evamarie
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600084
Subject(s) - phosphinidene , chemistry , yield (engineering) , ligand (biochemistry) , nuclear magnetic resonance spectroscopy , stereochemistry , crystallography , inorganic chemistry , biochemistry , materials science , receptor , metallurgy
The terminal phosphanyl phosphinidene complex [Cp*Ta(Ph)(P 6 Ph 5 )] ( 2 ) has been isolated in 16 % yield from the reaction of [Cp*TaCl 4 ] with 2 equiv. Na 2 (P 4 Ph 4 ) and displays an η 4 ‐bound (P 6 Ph 5 ) 3– ligand according to X‐ray crystallography and 31 P NMR spectroscopy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)