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Valence Tautomerism: New Challenges for Electroactive Ligands (Eur. J. Inorg. Chem. 15/2005)
Author(s) -
Evangelio Emilia,
RuizMolina Daniel
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200590032
Subject(s) - tautomer , chemistry , valence (chemistry) , intramolecular force , electron transfer , redox , ion , schematic , computational chemistry , stereochemistry , photochemistry , inorganic chemistry , organic chemistry , electronic engineering , engineering
The cover picture shows the potential energy curves for a generic valence tautomeric complex with a schematic representation emphasizing the intramolecular electron transfer between the metal ion and the ligand, which can be induced by different external stimuli such as temperature, pressure or irradiation. The diagram is accompanied by a representation of the different redox‐active ligands involved in valence tautomerism that are presented in the Microreview by E. Evangelio and D. Ruiz‐Molina on p. 2957 ff.