Synthesis, Molecular Structure and Reactivity of a Calix[4]arene Monomethyl Ether Supported Nitridomolybdenum Complex (Eur. J. Inorg. Chem. 11/2005) | Zendy

Deplano Paola | Zendy; Zeller Jürgen | Zendy; Büschel Susanne | Zendy; Reiser Benjamin K. H. | Zendy; Begum Farida | Zendy; Radius Udo | Zendy

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Synthesis, Molecular Structure and Reactivity of a Calix[4]arene Monomethyl Ether Supported Nitridomolybdenum Complex (Eur. J. Inorg. Chem. 11/2005)

Author(s) -

Deplano Paola,

Zeller Jürgen,

Büschel Susanne,

Reiser Benjamin K. H.,

Begum Farida,

Radius Udo

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200590024

Subject(s) - chemistry , ether , halide , reactivity (psychology) , metal halides , metal , yield (engineering) , crystallography , polymer chemistry , calixarene , group (periodic table) , stereochemistry , medicinal chemistry , molecule , organic chemistry , pathology , metallurgy , medicine , materials science , alternative medicine

The cover picture shows the reaction of a calix[4]arene methyl ether stabilized nitridomolybdenum complex [MoN(MeCalix)] with GaCl 3 to yield the compound [Mo(NGa‐Cl 3 )(MeCalix)]. This complex represents the first structurally characterized example of a nitrido‐bridged dinuclear compound of a group 6 metal and a group 13 halide [EX 3 ]. Both metal atoms are unsymmetrically bridged with a short [Mo≡N] and a long [Ga−N] contact. Details on synthesis and structural characterization are discussed in the article by U. Radius et al. on p. 2037 ff. In the background there is a view from the University of Karlsruhe (TH) to the adjacent “Hardtwald” on a stormy day photographed by Bernhard Mühr (www.wolkenatlas.de).

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