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Rational Design and Control of the Dimensions of Channels in Three‐Dimensional, Porous Metal‐Organic Frameworks Constructed with Predesigned Hexagonal Layers and Pillars
Author(s) -
Li CuiJin,
Hu Sheng,
Li Wei,
Lam ChiKeung,
Zheng YanZhen,
Tong MingLiang
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200501121
Subject(s) - microporous material , chemistry , hexagonal crystal system , metal organic framework , porosity , adsorption , rational design , metal , chemical engineering , nanotechnology , crystallography , inorganic chemistry , organic chemistry , materials science , engineering
New three‐dimensional, microporous metal‐organic frameworks exhibiting reversible water adsorption, constructed from hexagonal [Co 3 (imda) 2 ] layers and N , N′ ‐pillars, in which the dimensions of the channels are rationally adjustable by varying the lengths of pillars, have been designed, hydrothermally synthesized, and characterized. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)