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A Coordination Polymer Containing Inorganic Buckybowl Analogues
Author(s) -
Wu Tao,
Chen Miao,
Li Dan
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200501105
Subject(s) - chemistry , luminescence , ligand (biochemistry) , polymer , photoluminescence , metal , molecule , chelation , metal organic framework , fullerene , coordination complex , coordination polymer , polymer chemistry , inorganic chemistry , organic chemistry , biochemistry , physics , receptor , optoelectronics , adsorption , optics
Two photoluminescent coordination polymers, {[Cu 10 (μ 3 ‐Mtta) 3 (μ 4 ‐Mtta) 7 ] · 2H 2 O} n ( 1 ), containing 2‐D wavy motifs with inorganic buckybowl analogues, and [Cu 5 (μ 3 ‐Mtta) 2 (μ 4 ‐Mtta) 3 (NH 3 ) 2 ] n ( 2 , Mtta = 5‐methyl tetrazolate), were obtained by the control of solvents and auxiliary complexing agent. The ligand Mtta is a likely candidate for the construction of metal‐organic, fullerene‐like molecules. The luminescent properties of 1 and 2 are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)