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Photoinduced Phase Transition of the Coordinationally Unsaturated d 9 Metal Centers of Bis( N , N ‐diethylethylenediamine)copper( II ) Perchlorate within the Thermal Hysteresis of the Spin‐Exchange Interaction
Author(s) -
Naumov Panče,
Sakurai Kenji,
Asaka Toru,
Belik Alexei A.,
Adachi Shinichi,
Takahashi Junichi,
Koshihara Shinya
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200501058
Subject(s) - chemistry , copper , perchlorate , antiferromagnetism , excitation , transition metal , ferromagnetism , phase transition , crystallography , hysteresis , phase (matter) , diffraction , inorganic chemistry , condensed matter physics , ion , organic chemistry , physics , engineering , optics , electrical engineering , catalysis
Diffraction evidence is presented that the structure of one‐dimensional arrays of strained, coordinationally unsaturated d 9 pseudo‐Jahn–Teller centers of bis( N , N ‐diethylethylenediamine)copper( II ) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low‐temperature ferromagnetic‐to‐antiferromagnetic phase transition. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)