A 3D Manganese Coordination Polymer [Mn 3 (IMDC) 2 (H 2 O) 4 ] Constructed from [Mn 2 (IMDC) 2 (H 2 O) 2 ] Layers and [Mn(H 2 O) 2 ] Pillars (IMDC = 4,5‐imidazoledicarboxylate) | Zendy

Zhang ManBo | Zendy; Chen YongMei | Zendy; Zheng ShouTian | Zendy; Yang GuoYu | Zendy

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A 3D Manganese Coordination Polymer [Mn 3 (IMDC) 2 (H 2 O) 4 ] Constructed from [Mn 2 (IMDC) 2 (H 2 O) 2 ] Layers and [Mn(H 2 O) 2 ] Pillars (IMDC = 4,5‐imidazoledicarboxylate)

Author(s) -

Zhang ManBo,

Chen YongMei,

Zheng ShouTian,

Yang GuoYu

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500883

Subject(s) - chemistry , manganese , antiferromagnetism , crystallography , infrared spectroscopy , inorganic chemistry , polymer , coordination polymer , analytical chemistry (journal) , crystal structure , organic chemistry , condensed matter physics , physics

A novel three‐dimensional coordination polymer[Mn 3 (IMDC) 2 (H 2 O) 4 ] ( 1 ) (IMDC = 4,5‐imidazoledicarboxylate),consisting of [Mn 2 (IMDC) 2 (H 2 O) 2 ] layers and [Mn(H 2 O) 2 ]pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5‐imidazoledicarboxylate in the family of manganese complexes. Variable‐temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the Mn II ions of the dimeric units. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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