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A 3D Manganese Coordination Polymer [Mn 3 (IMDC) 2 (H 2 O) 4 ] Constructed from [Mn 2 (IMDC) 2 (H 2 O) 2 ] Layers and [Mn(H 2 O) 2 ] Pillars (IMDC = 4,5‐imidazoledicarboxylate)
Author(s) -
Zhang ManBo,
Chen YongMei,
Zheng ShouTian,
Yang GuoYu
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500883
Subject(s) - chemistry , manganese , antiferromagnetism , crystallography , infrared spectroscopy , inorganic chemistry , polymer , coordination polymer , analytical chemistry (journal) , crystal structure , organic chemistry , condensed matter physics , physics
A novel three‐dimensional coordination polymer[Mn 3 (IMDC) 2 (H 2 O) 4 ] ( 1 ) (IMDC = 4,5‐imidazoledicarboxylate),consisting of [Mn 2 (IMDC) 2 (H 2 O) 2 ] layers and [Mn(H 2 O) 2 ]pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5‐imidazoledicarboxylate in the family of manganese complexes. Variable‐temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the Mn II ions of the dimeric units. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)