Dinuclear Lanthanide Schiff‐Base Complexes Forming a Rectangular Columnar Mesophase | Zendy

Binnemans Koen | Zendy; Lodewyckx Katleen | Zendy; Cardinaels Thomas | Zendy; ParacVogt Tatja. | Zendy; Bourgogne Cyril | Zendy; Guillon Daniel | Zendy; Donnio Bertrand | Zendy

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Dinuclear Lanthanide Schiff‐Base Complexes Forming a Rectangular Columnar Mesophase

Author(s) -

Binnemans Koen,

Lodewyckx Katleen,

Cardinaels Thomas,

ParacVogt Tatja.,

Bourgogne Cyril,

Guillon Daniel,

Donnio Bertrand

Publication year - 2006

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500702

Subject(s) - lanthanide , mesophase , schiff base , chemistry , crystallography , tris , condensation , ion , polymer chemistry , organic chemistry , phase (matter) , thermodynamics , biochemistry , physics

The Schiff base L H 3 obtained by condensation of 3‐formyl‐4‐hydroxyphenyl‐3,4,5‐tris(tetradecyloxy)benzoate with 1,3‐diamino‐2‐propanol reacts with lanthanide( III ) acetate salts to form dinuclear complexes of the type Ln 2 L 2 with the trivalent ions from the first half of the lanthanide series (Ln = Nd, Sm, Gd). These stable and neutral metallomesogens exhibit a rectangular columnar mesophase over a broad temperature range. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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