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Significance of Intermolecular S···C(π) Interaction Involving M–S and –C=O Centers in Crystal Structures of Metal Thiolate Complexes
Author(s) -
Lewiński Janusz,
Bury Wojciech,
Justyniak Iwona
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500668
Subject(s) - chemistry , intermolecular force , non covalent interactions , metal , atom (system on chip) , crystallography , lewis acids and bases , sulfur , crystal structure , intermolecular interaction , stereochemistry , computational chemistry , molecule , organic chemistry , catalysis , hydrogen bond , computer science , embedded system
The database analysis of intermolecular S ··· C(π) distances involving a metal‐bonded thiolate sulfur atom and various C(π)‐centered Lewis acid domains provided evidences for M–S ··· C(π) contacts as resulting from specific noncovalent interactions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)