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From Molecular Double‐Ladders to an Unprecedented Polycatenation: A Parallel Catenated 3D Network Containing Bicapped Keggin Polyoxometalate Clusters
Author(s) -
Shi Zhenyu,
Gu Xiaojun,
Peng Jun,
Yu Xia,
Wang Enbo
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500662
Subject(s) - chemistry , catenation , polyoxometalate , crystallography , diamondoid , bipyridine , stereochemistry , catalysis , molecule , crystal structure , organic chemistry , dna , biochemistry
A new three‐dimensional coordination polymer, {Cu 3 (4,4′‐bpy) 3 (H 2 O)[PMo 12 O 40 (VO) 2 ] · 5H 2 O} n ( 1 ) (4,4′‐bpy = 4,4′‐bipyridine), which represents the first example of 3D polycatenation generated by unprecedented parallel catenation of the 1D double ladders, has been hydrothermally synthesized. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)