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Self‐Assembly of 1‐D Coordination Polymers Using Organometallic Linkers and Exhibiting Argentophilic Interactions Ag I ···Ag I
Author(s) -
Moussa Jamal,
Boubekeur Kamal,
Amouri Hani
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500605
Subject(s) - chemistry , group 2 organometallic chemistry , crystallography , polymer , organometallic chemistry , single crystal , self assembly , x ray crystallography , crystal structure , diffraction , polymer chemistry , stereochemistry , molecule , organic chemistry , physics , optics
Treatment of the organometallic linkers [Cp*M(η 4 ‐benzoquinone)] [M = Rh, L Rh , ( 1a ); M = Ir, L Ir ( 1b )] with excess AgOTf provided the novel 1‐D coordination polymers of the formula {[Ag 3 (L M ) 2 (CH 3 CN) 2 (OTf)][L M ](OTf) 2 } n ( 2a , b ). Single‐crystal X‐ray diffraction studies carried out on 2a and 2b showed that these polymers exhibit, as an outstanding feature, the presence of d 10 ··· d 10 argentophilic interactions between the silver atoms. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)