A Lutetium Cyclopentadienyl‐Phosphazene Constrained Geometry Complex (CGC): First Isolobal Analogues of Group 4 Cyclopentadienyl‐Silylamido CGC Systems | Zendy

Rufanov Konstantin A. | Zendy; Petrov Alex R. | Zendy; Kotov Vasili V. | Zendy; Laquai Frédéric | Zendy; Sundermeyer Jörg | Zendy

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A Lutetium Cyclopentadienyl‐Phosphazene Constrained Geometry Complex (CGC): First Isolobal Analogues of Group 4 Cyclopentadienyl‐Silylamido CGC Systems

Author(s) -

Rufanov Konstantin A.,

Petrov Alex R.,

Kotov Vasili V.,

Laquai Frédéric,

Sundermeyer Jörg

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500529

Subject(s) - cyclopentadienyl complex , phosphazene , chemistry , lutetium , group (periodic table) , azide , stereochemistry , medicinal chemistry , organic chemistry , catalysis , yttrium , oxide , polymer

C 5 Me 4 HPMe 2 reacts with 1‐adamantyl azide to form the firstexample of a new family of cyclopentadienylideneaminophosphorane ligands ( 1 ). Metallation of 1 with Lu(CH 2 SiMe 3 ) 3 (THF) 2 leads to the first cyclopentadienyl‐phosphazene CGC 2 , isolobal to known group 4 cyclopentadienyl‐silylamido CGC systems. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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