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A Lutetium Cyclopentadienyl‐Phosphazene Constrained Geometry Complex (CGC): First Isolobal Analogues of Group 4 Cyclopentadienyl‐Silylamido CGC Systems
Author(s) -
Rufanov Konstantin A.,
Petrov Alex R.,
Kotov Vasili V.,
Laquai Frédéric,
Sundermeyer Jörg
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500529
Subject(s) - cyclopentadienyl complex , phosphazene , chemistry , lutetium , group (periodic table) , azide , stereochemistry , medicinal chemistry , organic chemistry , catalysis , yttrium , oxide , polymer
C 5 Me 4 HPMe 2 reacts with 1‐adamantyl azide to form the firstexample of a new family of cyclopentadienylideneaminophosphorane ligands ( 1 ). Metallation of 1 with Lu(CH 2 SiMe 3 ) 3 (THF) 2 leads to the first cyclopentadienyl‐phosphazene CGC 2 , isolobal to known group 4 cyclopentadienyl‐silylamido CGC systems. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)