A Novel Five‐Coordinate Rhodium( I ) Complex | Zendy

Koshevoy Igor O. | Zendy; Sizova Olga V. | Zendy; Tunik Sergey P. | Zendy; Lough Alan | Zendy; Poë Anthony J. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Novel Five‐Coordinate Rhodium( I ) Complex

Author(s) -

Koshevoy Igor O.,

Sizova Olga V.,

Tunik Sergey P.,

Lough Alan,

Poë Anthony J.

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500444

Subject(s) - chemistry , rhodium , trigonal bipyramidal molecular geometry , nuclear magnetic resonance spectroscopy , crystallography , molecule , stereochemistry , trigonal crystal system , crystal structure , catalysis , organic chemistry

An unusual five‐coordinate isomer of the mononuclear complex [Rh(CO) 2 (PPh 3 ) 2 I] has been isolated, and its crystallographic structure determined. The molecule has a slightly distorted trigonal‐bipyramidal structure, with both PPh 3 ligands being in axial positions. A combination of IR and NMR spectroscopy with the results of DFT calculations shows that the complex maintains the same structure in solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research