Nonlinear Optical Activity and High Thermal Stability of a New 3DOpen‐Framework with Interconnected 24‐, 16‐, and 8‐Atom Channels: (NH 4 )Zn[O 3 PCH(OH)CO 2 ] | Zendy

Fu Ruibiao | Zendy; Zhang Huishuang | Zendy; Wang Longsheng | Zendy; Hu Shengmin | Zendy; Li Yaming | Zendy; Huang Xihe | Zendy; Wu Xintao | Zendy

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Nonlinear Optical Activity and High Thermal Stability of a New 3DOpen‐Framework with Interconnected 24‐, 16‐, and 8‐Atom Channels: (NH 4 )Zn[O 3 PCH(OH)CO 2 ]

Author(s) -

Fu Ruibiao,

Zhang Huishuang,

Wang Longsheng,

Hu Shengmin,

Li Yaming,

Huang Xihe,

Wu Xintao

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500347

Subject(s) - chemistry , zinc , acetic acid , thermal stability , hydrothermal circulation , phosphate , potassium , hydrothermal synthesis , ammonium acetate , atom (system on chip) , zinc phosphate , inorganic chemistry , nonlinear optical , crystallography , nuclear chemistry , organic chemistry , chemical engineering , nonlinear system , physics , high performance liquid chromatography , quantum mechanics , computer science , embedded system , engineering

Hydrothermal reaction of hydroxy(phosphono)acetic acid, H 2 O 3 PCH(OH)CO 2 H, with zinc( II ) acetate resulted in a new ammonium zinc hydroxy(phosphonato)acetate, (NH 4 )Zn[O 3 PCH(OH)CO 2 ] ( 1 ). The structure of 1 contains a 3D open‐framework consisting of interconnected 24‐, 16‐, and 8‐atom channels. TGA and XRD reveal that the framework is stable up to 350 °C in air. Its powder SHG intensity is about 0.8 times that of potassium dihydrogen phosphate KDP. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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