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An Unprecedented One‐Dimensional Chain Constructed from β‐Octamolybdate Clusters and Two Kinds of Silver Complex Fragments
Author(s) -
Shi Zhenyu,
Gu Xiaojun,
Peng Jun,
Xin Zhifeng
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500330
Subject(s) - chemistry , phenazine , hydrothermal circulation , ligand (biochemistry) , fluorescence , crystallography , bipyridine , hydrothermal reaction , hydrothermal synthesis , stereochemistry , polymer chemistry , organic chemistry , crystal structure , chemical engineering , biochemistry , physics , receptor , quantum mechanics , engineering
An unprecedented one‐dimensional chainlike compound with green fluorescent emission, (H 3 O)[Ag 3 (2,2′‐bpy) 2 (phnz) 2 (β‐Mo 8 O 26 )] (bpy = bipyridine, phnz = phenazine) has been synthesized under hydrothermal conditions. The compound is constructed from β‐octamolybdate clusters linked through two kinds of silver‐ligand subunits, [Ag(2,2′‐bpy)(phnz)] + and [Ag(phnz)] + . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)