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Two Novel Cadmium Polymeric Metallamacrocyclic Complexes Constructed from a Pyridylmethyl‐Functionalized Tetraaza Ligand
Author(s) -
Ma Zhen,
Chen Zhongning,
Cao Rong
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500288
Subject(s) - chemistry , cyclam , ligand (biochemistry) , cadmium , hydrothermal circulation , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , metal , chemical engineering , biochemistry , receptor , engineering
A new octadentate ligand L was synthesized by tetrafunctionalization of 1,4,8,11‐tetraazacyclotetradecane (L 1 , cyclam) with 4‐pyridylmethyl groups and its two novelcadmium polymeric metallamacrocyclic complexes, [Cd 3 L 1.5 (C 6 H 5 O 7 ) 2 ·6H 2 O] n ( 1 ) and [CdCl 2 L 2 ·2.5H 2 O] n ( 2 ), were obtained by hydrothermal methods. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)