Synthesis and Crystal Structure of a Cocrystalline Compound of a Rare Earth Metalloporphyrin with Fullerene {[TPPYb(μ‐OH) 2 Yb(THF)TPP]·C 60 }  n | Zendy

Zhang Jie | Zendy; Cai Ruifang | Zendy; Chen Minqing | Zendy; Weng Linhong | Zendy; Zhou Xigeng | Zendy

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Synthesis and Crystal Structure of a Cocrystalline Compound of a Rare Earth Metalloporphyrin with Fullerene {[TPPYb(μ‐OH) 2 Yb(THF)TPP]·C 60 } n

Author(s) -

Zhang Jie,

Cai Ruifang,

Chen Minqing,

Weng Linhong,

Zhou Xigeng

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500229

Subject(s) - chemistry , cocrystal , crystal structure , toluene , supramolecular chemistry , tetraphenylporphyrin , metallofullerene , fullerene , lanthanide , crystallography , rare earth , stereochemistry , photochemistry , molecule , porphyrin , organic chemistry , ion , hydrogen bond , mineralogy

The reaction of YbI 2 (THF) 2 with TPPLi 2 (TPP = 5,10,15,20‐tetraphenylporphyrin) in THF, and then with 0.5 equiv. of C 60 , which was solvated in toluene beforehand, gave the title compound {[TPPYb(μ‐OH) 2 Yb(THF)TPP] · C 60 } n , which is the first example of a rare earth metallofullerene cocrystal compound. X‐ray structural analyses indicate that this compound displays a complicated supramolecular structure, which contains some unique noncovalent interactionsbetween C 60 and the rare earth metalloporphyrin units. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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