Spectroscopy and Redox Behaviour of Dicopper( II ) and Dinickel( II ) Complexes of Bis(cyclen) and Bis(cyclam) Ligands | Zendy

El Ghachtouli Sanae | Zendy; Cadiou Cyril | Zendy; DéchampsOlivier Isabelle | Zendy; Chuburu Françoise | Zendy; Aplincourt Michel | Zendy; Turcry Véronique | Zendy; Le Baccon Michel | Zendy; Handel Henri | Zendy

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Spectroscopy and Redox Behaviour of Dicopper( II ) and Dinickel( II ) Complexes of Bis(cyclen) and Bis(cyclam) Ligands

Author(s) -

El Ghachtouli Sanae,

Cadiou Cyril,

DéchampsOlivier Isabelle,

Chuburu Françoise,

Aplincourt Michel,

Turcry Véronique,

Le Baccon Michel,

Handel Henri

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200500120

Subject(s) - chemistry , cyclam , cyclen , copper , electrochemistry , electron paramagnetic resonance , redox , metal , crystallography , spectroscopy , stereochemistry , inorganic chemistry , organic chemistry , electrode , nuclear magnetic resonance , physics , quantum mechanics

The dinuclear Cu II and Ni II complexes of meta ‐xylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N( py ) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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