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A Binuclear Copper( II ) Complex Containing the Pyrazine‐2,5‐dicarboxylate Ligand: Study of the Magnetic Exchange through the Pyrazine Bridge
Author(s) -
Beobide Garikoitz,
Castillo Oscar,
GarcíaCouceiro Urko,
GarcíaTerán Juan P.,
Luque Antonio,
MartínezRipoll Martín,
Román Pascual
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200500119
Subject(s) - pyrazine , chemistry , copper , ligand (biochemistry) , crystallography , bridge (graph theory) , phenanthroline , stereochemistry , organic chemistry , receptor , medicine , biochemistry
Abstract The compound [Cu 2 (μ‐pzdc)(phen) 4 ](NO 3 ) 2 · 10H 2 O ( 1 ; pzdc = pyrazine‐2,5‐dicarboxylato; phen = 1,10‐phenanthroline) has been structurally and magnetically characterised. Theoretical calculations have allowed us to establish a plausible magneto‐structural correlation for pyrazine‐bridged complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)