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First Complexes of a 4‐Alkyl‐3,5‐di(2‐pyridyl)‐4 H ‐1,2,4‐triazole: Synthesis,X‐ray Crystal Structures and Magnetic Properties of Dinuclear Cobalt( II ), Nickel( II ) and Copper( II ) Complexes of 4‐Isobutyl‐3,5‐di(2‐pyridyl)‐4 H ‐1,2,4‐triazole
Author(s) -
Klingele Marco H.,
Boyd Peter D. W.,
Moubaraki Boujemaa,
Murray Keith S.,
Brooker Sally
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200400780
Subject(s) - chemistry , denticity , crystallography , homoleptic , ligand (biochemistry) , cobalt , octahedron , metal , crystal structure , alkyl , stereochemistry , hydrogen bond , medicinal chemistry , molecule , inorganic chemistry , organic chemistry , biochemistry , receptor
The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4 H ‐1,2,4‐triazole (ibdpt) with M(ClO 4 ) 2 · 6H 2 O (M = Co II , Ni II or Cu II ) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co II 2 (ibdpt) 2 (MeCN) 2 (H 2 O) 2 ](ClO 4 ) 4 ( 1 ), [Ni II 2 ‐(ibdpt) 2 ‐(MeCN) 4 ](ClO 4 ) 4 ( 2 ) and [Cu II 2 (ibdpt) 2 (MeCN) 2 ‐(ClO 4 ) 2 ]‐(ClO 4 ) 2 · 2MeCN ( 3 ). Complex 1 is obtained as a mixture of the red‐orange polymorph 1a and the yellow‐orange polymorph 1b , the main difference between the two forms being the hydrogen bonding patterns between the H 2 O co‐ligands and the ClO 4 – counterions. The mononuclear complex [Cu II ‐(ibdpt) 2 (ClO 4 ) 2 ] ( 4 ) was initially obtained as a minor by‐product in the preparation of complex 3 but can also be deliberately prepared from Cu(ClO 4 ) 2 · 6H 2 O and ibdpt in MeCN using a metal‐to‐ligand molar ratio of 1:2. All five complexes have been structurally characterised by X‐ray diffraction. In the dinuclear complexes 1 – 3 the ( N , N 1 , N 2 , N ) 2 double bridging coordination mode is realised while the mononuclear complex 4 features the common trans ‐( N , N 1 ) 2 coordination mode. In all cases the metal centres reside in distorted octahedral N 4 X 2 coordination spheres with axially bound co‐ligands (X = H 2 O, MeCN or ClO 4 – ). The dinuclear complexes 1 – 3 readily lose solvent when taken out of their mother liquors giving rise to partially desolvated materials. Magnetic studies have been carried out on crystalline samples of the resulting complexes that analysed as Co II 2 ‐(ibdpt) 2 (ClO 4 ) 4 ‐(MeCN)(H 2 O) ( 5 ), Ni II 2 (ibdpt) 2 (ClO 4 ) 4 (MeCN) ( 6 ) and Cu II 2 ‐(ibdpt) 2 (ClO 4 ) 4 (MeCN) ( 7 ). It was found that in these complexes the two 1,2,4‐triazole bridges facilitate antiferro‐magnetic coupling between the two metal centres ( J =–3.76 cm –1 , –13.0 cm –1 and –105 cm –1 , respectively). The coordination compounds described in this paper are the first to incorporate a 4‐alkyl‐substituted 3,5‐di(2‐pyridyl)‐4 H ‐1,2,4‐triazole ligand. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)