Oxidation of a One‐Dimensional Coordination Polymer and Synthesis of the Macrocyclic Silver Complex [Ag 12 (PhS 2 P−PS 2 Ph) 6 (dppeS) 6 ] | Zendy

Fenske Dieter | Zendy; Rothenberger Alexander | Zendy; Fallah Maryam Shafaei | Zendy

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Oxidation of a One‐Dimensional Coordination Polymer and Synthesis of the Macrocyclic Silver Complex [Ag 12 (PhS 2 P−PS 2 Ph) 6 (dppeS) 6 ]

Author(s) -

Fenske Dieter,

Rothenberger Alexander,

Fallah Maryam Shafaei

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400738

Subject(s) - chemistry , reagent , transition metal , trimethylsilyl , polymer , ligand (biochemistry) , coordination polymer , metal , coordination complex , polymer chemistry , stereochemistry , crystallography , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , biochemistry , receptor

The cluster chemistry with functionalised trimethylsilyl reagents was investigated. The oxidation of the one‐dimensional coordination polymer 1/ ∞ [{Ag 2 (PhS 2 P−PS 2 Ph)dppe}·dppe] ∞ leads to the formation of [Ag 12 (PhS 2 P−PS 2 Ph) 6 (dppeS) 6 ] (dppeS = Ph 2 P(CH 2 ) 2 P(S)Ph 2 ]. The dianionic ligand [PhPS 2 −PS 2 Ph] 2− could possibly give rise to a new class of macrocyclic transition‐metal chalcogenides. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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