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Oxidation of a One‐Dimensional Coordination Polymer and Synthesis of the Macrocyclic Silver Complex [Ag 12 (PhS 2 P−PS 2 Ph) 6 (dppeS) 6 ]
Author(s) -
Fenske Dieter,
Rothenberger Alexander,
Fallah Maryam Shafaei
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200400738
Subject(s) - chemistry , reagent , transition metal , trimethylsilyl , polymer , ligand (biochemistry) , coordination polymer , metal , coordination complex , polymer chemistry , stereochemistry , crystallography , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , biochemistry , receptor
The cluster chemistry with functionalised trimethylsilyl reagents was investigated. The oxidation of the one‐dimensional coordination polymer 1/ ∞ [{Ag 2 (PhS 2 P−PS 2 Ph)dppe}·dppe] ∞ leads to the formation of [Ag 12 (PhS 2 P−PS 2 Ph) 6 (dppeS) 6 ] (dppeS = Ph 2 P(CH 2 ) 2 P(S)Ph 2 ]. The dianionic ligand [PhPS 2 −PS 2 Ph] 2− could possibly give rise to a new class of macrocyclic transition‐metal chalcogenides. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)