Channel Structures in a Simple Inorganic Salt − An Open Framework Formed through Structural Integration of Distinct Sodium Acetate and Sodium Perchlorate Domains | Zendy

Lavalette Arnaud | Zendy; Lawrance Geoffrey A. | Zendy; Alcock Nathaniel W. | Zendy; Han Michael J. | Zendy

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Channel Structures in a Simple Inorganic Salt − An Open Framework Formed through Structural Integration of Distinct Sodium Acetate and Sodium Perchlorate Domains

Author(s) -

Lavalette Arnaud,

Lawrance Geoffrey A.,

Alcock Nathaniel W.,

Han Michael J.

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400365

Subject(s) - chemistry , sodium perchlorate , supramolecular chemistry , perchlorate , sodium , salt (chemistry) , sodium acetate , inorganic chemistry , crystal structure , sodium salt , crystallography , organic chemistry , ion , electrochemistry , electrode

The novel mixed salt of sodium acetate and perchlorate reported herein, Na 4 (OAc) 3 (ClO 4 ), has a distinctive lattice structure formed from sodium acetate planes linked together by sodium perchlorate cylinders. In total contrast to the component salts, the structure contains channels parallel to the c axis. The integration of the two molecular‐level structural motifs of the two component salts thus leads to a supramolecular/macromolecular‐level structure which is very different from those of the components. A template mechanism is implicated in the formation. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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