Methyl Substitution of Aluminum−Hydride Bonds in a Carbaalane and an Aluminum Imide | Zendy

Stasch Andreas | Zendy; Shravan Kumar S. | Zendy; Jancik Vojtech | Zendy; Roesky Herbert W. | Zendy; Magull Jörg | Zendy; Noltemeyer Mathias | Zendy

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Methyl Substitution of Aluminum−Hydride Bonds in a Carbaalane and an Aluminum Imide

Author(s) -

Stasch Andreas,

Shravan Kumar S.,

Jancik Vojtech,

Roesky Herbert W.,

Magull Jörg,

Noltemeyer Mathias

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400347

Subject(s) - chemistry , toluene , hydride , solvent , medicinal chemistry , aluminum hydride , imide , crystal structure , molecule , aluminium , stereochemistry , crystallography , polymer chemistry , organic chemistry , catalysis , hydrogen , methoxide

The methylated compounds [(AlMe) 6 (AlNMe 3 ) 2 (CCH 2 Ph) 6 ] ( 4 ), [(AlMe) 6 (AlNMe 3 ) 2 (CCH 2 CH 2 SiMe 3 ) 6 ] ( 5 ) and [(AlMe) 6 (NCH 2 C 4 H 3 S) 6 ] ( 6 ) were synthesized in good yields from the corresponding hydride derivatives by treatment with AlMe 3 in toluene. The X‐ray single crystal structures of 4· x C 7 H 8 , 4· 4C 7 H 8 and 6 were determined. In 4· x C 7 H 8 the solvent molecules are arranged in infinite channels along the c axis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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