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Methyl Substitution of Aluminum−Hydride Bonds in a Carbaalane and an Aluminum Imide
Author(s) -
Stasch Andreas,
Shravan Kumar S.,
Jancik Vojtech,
Roesky Herbert W.,
Magull Jörg,
Noltemeyer Mathias
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200400347
Subject(s) - chemistry , toluene , hydride , solvent , medicinal chemistry , aluminum hydride , imide , crystal structure , molecule , aluminium , stereochemistry , crystallography , polymer chemistry , organic chemistry , catalysis , hydrogen , methoxide
The methylated compounds [(AlMe) 6 (AlNMe 3 ) 2 (CCH 2 Ph) 6 ] ( 4 ), [(AlMe) 6 (AlNMe 3 ) 2 (CCH 2 CH 2 SiMe 3 ) 6 ] ( 5 ) and [(AlMe) 6 (NCH 2 C 4 H 3 S) 6 ] ( 6 ) were synthesized in good yields from the corresponding hydride derivatives by treatment with AlMe 3 in toluene. The X‐ray single crystal structures of 4· x C 7 H 8 , 4· 4C 7 H 8 and 6 were determined. In 4· x C 7 H 8 the solvent molecules are arranged in infinite channels along the c axis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)