From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3 ) 2  Assembly Featuring One‐Dimensional (AgCl 3 ) 2−  Anions | Zendy

Oleneva Olga S. | Zendy; Olenev Andrei V. | Zendy; Dikarev Evgeny V. | Zendy; Shevelkov Andrei V. | Zendy

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From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3 ) 2 Assembly Featuring One‐Dimensional (AgCl 3 ) 2− Anions

Author(s) -

Oleneva Olga S.,

Olenev Andrei V.,

Dikarev Evgeny V.,

Shevelkov Andrei V.

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400205

Subject(s) - chemistry , supramolecular chemistry , monoclinic crystal system , cationic polymerization , crystallography , moiety , tetrahedron , crystal structure , mercury (programming language) , stereochemistry , polymer chemistry , computer science , programming language

A novel supramolecular assembly [Hg 6 As 4 ](AgCl 3 ) 2 has been prepared and its structure determined. It crystallizes in the monoclinic system, space group I 2/ a (no. 15), with the unit‐cell dimensions a = 14.690(1), b = 9.1851(7), c = 20.285(1) Å, β = 93.17(1)°, and Z = 4. The crystal structure comprises a three‐dimensional cationic host framework, [Hg 6 As 4 ] 4+ , built of mercury and arsenic atoms and one‐dimensional ∞ 1 (AgCl 3 ) 2− guest anions built of corner‐sharing [AgCl 4 ] tetrahedra. The title compound is the first example of a perfectly ordered supramolecular architecture having an infinite chain anion as a guest moiety embedded into a mercury−pnicogen cationic framework. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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