The Redox Chemistry of SbF 6  −  Ion | Zendy

Ponikvar Maja | Zendy; Liebman Joel F. | Zendy; Jenkins H. Donald B. | Zendy

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The Redox Chemistry of SbF 6 − Ion

Author(s) -

Ponikvar Maja,

Liebman Joel F.,

Jenkins H. Donald B.

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400150

Subject(s) - chemistry , oxidizing agent , counterion , redox , inorganic chemistry , ion , metal , coordination complex , organic chemistry

Chemical analysis of Sb in coordination compounds requires quantitative reduction of Sb V in the form of SbF 6 − (and its related fluoro‐hydroxy species) to Sb III . This process, although thermodynamically favoured, appears to be kinetically hindered. The experimentally observed stabilisation of SbF 6 − towards reduction, as happens when the associated metal counterion is complexed by XeF 2 (generally regarded as being an oxidizing agent), is also discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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