Ru II  Complexes of Bis(1,10‐phenanthrolin‐2‐yl)diazines | Zendy

Brown Darren | Zendy; Zong Ruifa | Zendy; Thummel Randolph P. | Zendy

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Ru II Complexes of Bis(1,10‐phenanthrolin‐2‐yl)diazines

Author(s) -

Brown Darren,

Zong Ruifa,

Thummel Randolph P.

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400144

Subject(s) - chemistry , pyridazine , pyrazine , electrochemistry , pyrimidine , ruthenium , bridging ligand , terpyridine , ligand (biochemistry) , ring (chemistry) , medicinal chemistry , stereochemistry , phenanthroline , crystallography , crystal structure , catalysis , metal , organic chemistry , electrode , biochemistry , receptor

A series of three bis‐tridentate bridging ligands has been prepared in which two 1,10‐phenanthroline units have been symmetrically appended to a central pyridazine, pyrimidine, or pyrazine ring. These ligands have been treated with [Ru(tpy‐ d 11 )Cl 3 ] to afford both mono‐ and dinuclear complexes whose photo‐ and electrochemical properties have been evaluated (tpy = 2,2′:6′,2′′‐terpyridine). A structural comparison is made between [(tpy)Ru( 3 )Ru(tpy)](PF 6 ) 4 and a previously reported complex involving 2,2′‐bipyridines in place of phenanthrolines on the bridging ligand and surprisingly little difference is found. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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