3D‐Coordination Cluster Polymers [Ln(H 2 O) 3 Re 6 Te 8 (CN) 6 ]· n H 2 O (Ln = La 3+ , Nd 3+ ): Direct Structural Analogy with the Mononuclear LnM(CN) 6 · n H 2 O Family | Zendy

Artemkina Sofia B. | Zendy; Naumov Nikolai G. | Zendy; Virovets Alexander V. | Zendy; Fedorov Vladimir E. | Zendy

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3D‐Coordination Cluster Polymers [Ln(H 2 O) 3 Re 6 Te 8 (CN) 6 ]· n H 2 O (Ln = La 3+ , Nd 3+ ): Direct Structural Analogy with the Mononuclear LnM(CN) 6 · n H 2 O Family

Author(s) -

Artemkina Sofia B.,

Naumov Nikolai G.,

Virovets Alexander V.,

Fedorov Vladimir E.

Publication year - 2005

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200400139

Subject(s) - chemistry , crystallography , cluster (spacecraft) , group (periodic table) , hydrothermal circulation , hydrothermal synthesis , unit (ring theory) , stereochemistry , coordination number , ion , mathematics education , mathematics , organic chemistry , seismology , computer science , programming language , geology

Using the hydrothermal method two novel 3D‐coordination complexes [Ln(H 2 O) 3 Re 6 Te 8 (CN) 6 ]· n H 2 O (Ln = La 3+ , Nd 3+ ) have been synthesised and structurally characterised. For compound [La(H 2 O) 3 Re 6 Te 8 (CN) 6 ]·4H 2 O ( 1 ) the unit cell parameters are: Space group P 6 3 / m , a = 9.3060(13), c = 20.528(4) Å, V = 1539.6(4) Å 3 , R f = 0.0597. For compound [Nd(H 2 O) 3 Re 6 Te 8 (CN) 6 ]·H 2 O ( 2 ) the unit cell parameters are: Space group P 6 3 /m, a = 9.3030(10), c = 20.222(4) Å, V = 1515.7(4) Å 3 , R f = 0.0226. The structures of the cluster compounds are topologically analogous to the mononuclear polymeric complex LaCr(CN) 6 ·5H 2 O. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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