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A Three‐Dimensional Framework of Novel Vanadium Clusters Bridged by [Ni(en) 2 ] 2+ : Ni(en) 3 {V IV 11 V V 5 O 38 Cl [Ni (en) 2 ] 3 }·8.5H 2 O
Author(s) -
Pan ChengLing,
Xu JiQing,
Li GuangHua,
Chu DeQing,
Wang TieGang
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200390196
Subject(s) - chemistry , vanadium , crystallography , hydrothermal circulation , hydrothermal synthesis , transition metal , inorganic chemistry , catalysis , chemical engineering , biochemistry , engineering
The hydrothermal reaction of V 2 O 5 , H 2 C 2 O 4 ·2H 2 O, KOH, en and NiCl 2 ·6H 2 O yields a new three‐dimensional open‐framework solid. The extended structure consists of a three‐dimensional network of [V 16 O 38 Cl] 8− cages, with each cage connected to six other neighboring units through [Ni(en) 2 ] 2+ bridging groups. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)