A Three‐Dimensional Framework of Novel Vanadium Clusters Bridged by [Ni(en) 2 ] 2+ : Ni(en) 3 {V IV  11 V V  5 O 38  Cl [Ni (en) 2 ] 3 }·8.5H 2 O | Zendy

Pan ChengLing | Zendy; Xu JiQing | Zendy; Li GuangHua | Zendy; Chu DeQing | Zendy; Wang TieGang | Zendy

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A Three‐Dimensional Framework of Novel Vanadium Clusters Bridged by [Ni(en) 2 ] 2+ : Ni(en) 3 {V IV 11 V V 5 O 38 Cl [Ni (en) 2 ] 3 }·8.5H 2 O

Author(s) -

Pan ChengLing,

Xu JiQing,

Li GuangHua,

Chu DeQing,

Wang TieGang

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200390196

Subject(s) - chemistry , vanadium , crystallography , hydrothermal circulation , hydrothermal synthesis , transition metal , inorganic chemistry , catalysis , chemical engineering , biochemistry , engineering

The hydrothermal reaction of V 2 O 5 , H 2 C 2 O 4 ·2H 2 O, KOH, en and NiCl 2 ·6H 2 O yields a new three‐dimensional open‐framework solid. The extended structure consists of a three‐dimensional network of [V 16 O 38 Cl] 8− cages, with each cage connected to six other neighboring units through [Ni(en) 2 ] 2+ bridging groups. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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