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Sequential Nucleophilic−Electrophilic Reactions Selectively Produce Isomerically Pure Nona‐ B ‐Substituted o ‐Carborane Derivatives
Author(s) -
Barberà Gemma,
Teixidor Francesc,
Viñas Clara,
Sillanpää Reijo,
Kivekäs Raikko
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200390195
Subject(s) - chemistry , electrophile , nucleophile , carborane , medicinal chemistry , combinatorial chemistry , organic chemistry , catalysis
Nine equal substituents on the intensively studied o ‐carborane have been obtained for the first time by a combined nucleophilic‐electrophilic reaction sequence. Iodine and methyl groups have been introduced to prove the generality of the method. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)