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A Facile Synthesis of a Push‐Pull Mixed‐Ligand Pd‐Dithiolene Complex Containing the Et 2 timdt Ligand (Et 2 timdt = Monoreduced Diethylimidazolidine‐2,4,5‐trithione)
Author(s) -
Aragoni M. Carla,
Arca Massimiliano,
Denotti Carla,
Devillanova Francesco A.,
Grigiotti Emanuela,
Isaia Francesco,
Laschi Franco,
Lippolis Vito,
Pala Luca,
Slawin Alexandra M. Z.,
Zanello Piero,
Woollins J. Derek
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200390165
Subject(s) - chemistry , ligand (biochemistry) , medicinal chemistry , stereochemistry , combinatorial chemistry , receptor , biochemistry
The reaction of the dithiolene [Pd(Et 2 timdt) 2 ] (Et 2 timdt = formally monoreduced diethylimidazolidine‐2,4,5‐trithione) with Br 2 or IBr yields the complex [Pd(Et 2 timdt)Br 2 ], a good starting material for the synthesis of novel push‐pull mixed‐ligand Pd‐dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et 2 timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)