Cobalt Chloride Complexes of N 3  and N 4  Donor Ligands | Zendy

Kooistra T. Martijn | Zendy; Hekking Koen F. W. | Zendy; Knijnenburg Quinten | Zendy; de Bruin Bas | Zendy; Budzelaar Peter H. M. | Zendy; de Gelder René | Zendy; Smits Jan M. M. | Zendy; Gal Anton W. | Zendy

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Cobalt Chloride Complexes of N 3 and N 4 Donor Ligands

Author(s) -

Kooistra T. Martijn,

Hekking Koen F. W.,

Knijnenburg Quinten,

de Bruin Bas,

Budzelaar Peter H. M.,

de Gelder René,

Smits Jan M. M.,

Gal Anton W.

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200390090

Subject(s) - chemistry , cobalt , cationic polymerization , pyridine , chloride , amine gas treating , polymerization , paramagnetism , polymer chemistry , medicinal chemistry , inorganic chemistry , organic chemistry , polymer , physics , quantum mechanics

A number of cobalt( II ) chloride complexes of pyridine/amine N 3 and N 4 donors have been prepared and structurally characterised. Even though they are paramagnetic, assignment of the 1 H NMR signals was possible in several cases. With the exception of tpa, which formed a cationic monochloride complex, all new complexes have cis ‐coordinated chlorides. Nevertheless, only the relatively rigid pyp ligands gave rise to (low) ethene polymerisation activity on activation with MAO. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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