Investigations on 1‐Metallaindanes | Zendy

Goedheijt Marcel Schreuder | Zendy; Nijbacker Tom | Zendy; Horton Andrew D. | Zendy; Kanter Franciscus J. J. de | Zendy; Akkerman Otto S. | Zendy; Bickelhaupt Friedrich | Zendy

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Investigations on 1‐Metallaindanes

Author(s) -

Goedheijt Marcel Schreuder,

Nijbacker Tom,

Horton Andrew D.,

Kanter Franciscus J. J. de,

Akkerman Otto S.,

Bickelhaupt Friedrich

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200390088

Subject(s) - chemistry , trimer , dimer , adduct , methylene , boron , benzene , zirconium , fluorine , atom (system on chip) , magnesium , carbon atom , medicinal chemistry , ion , crystallography , inorganic chemistry , organic chemistry , ring (chemistry) , computer science , embedded system

1‐Mercuraindane ( 6 ) was prepared in three steps from 1‐bromo‐2‐(2‐bromoethyl)benzene ( 3 ) and converted into 1‐magnesaindane ( 1 ) by reaction with magnesium. In solution, 6 was observed to occur in a remarkable dimer/trimer equilibrium, whereas 1 forms a dimer. From 1 and dichlorozirconocene, the 1‐zirconaindane 2 was obtained, which reacted with B(C 6 F 5 ) 3 to form the adduct 13 . According to spectroscopic data, 13 is formed by attack of the β‐methylene carbon atom at the boron atom and has a zwitterionic structure with weak interactions between the zirconium ion and one of the ortho ‐fluorine atoms. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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