Direct Synthesis of Enantiopure Tripod Ligands from  C  2 ‐Symmetric Precursors | Zendy

Hegelmann Ina | Zendy; Burzlaff Nicolai | Zendy

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Direct Synthesis of Enantiopure Tripod Ligands from C 2 ‐Symmetric Precursors

Author(s) -

Hegelmann Ina,

Burzlaff Nicolai

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200390056

Subject(s) - tripod (photography) , enantiopure drug , chemistry , carboxylate , ligand (biochemistry) , stereochemistry , carbon atom , methane , combinatorial chemistry , organic chemistry , enantioselective synthesis , receptor , catalysis , alkyl , physics , optics , biochemistry

A new enantiopure chiral tripod ligand is obtained from C 2 ‐symmetric bis(camphorpyrazol‐1‐yl)methane by introducing a carboxylate group at the bridging carbon atom. A prochiral centre is formed rather than an additional stereocentre. Therefore, a homochiral tripod ligand is achieved without separation of the stereoisomers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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