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The Unexpected Formation of a Novel Fluorinated Triene
Author(s) -
Shevchenko Igor,
Andrushko Vasyl,
Lork Enno,
Röschenthaler GerdVolker
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200390007
Subject(s) - chemistry , trifluoromethyl , methane , solid state , medicinal chemistry , stereochemistry , organic chemistry , alkyl
Bis[bis(dialkylamino)phosphanyl]methane ( 1 ) and 4,4,4‐trifluoro‐3‐(trifluoromethyl)‐2‐butenenitrile ( 2 ) unexpectedly gave triene 3 . According to the X‐ray structure analysis compound 3 exists in the solid state exclusively as one isomer. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)