Self‐Assembly of a One‐Dimensional Silver Complex Containing Two Kinds of Helical Chains | Zendy

Sun Daofeng | Zendy; Cao Rong | Zendy; Sun Yanqiong | Zendy; Bi Wenhua | Zendy; Li Xing | Zendy; Hong Maochun | Zendy; Zhao Yingjun | Zendy

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Self‐Assembly of a One‐Dimensional Silver Complex Containing Two Kinds of Helical Chains

Author(s) -

Sun Daofeng,

Cao Rong,

Sun Yanqiong,

Bi Wenhua,

Li Xing,

Hong Maochun,

Zhao Yingjun

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200390003

Subject(s) - chemistry , piperazine , hydrogen bond , supramolecular chemistry , salt (chemistry) , crystallography , self assembly , sulfonate , potassium , stereochemistry , polymer chemistry , molecule , organic chemistry , sodium , crystal structure

Self‐assembly of the potassium sulfonate salt K 2 pesp [H 2 pesp = piperazine‐1,4‐bis(2‐ethanesulfonic acid] with piperazine (PIP) and a silver( I ) salt in solution allows the preparation of a novel one‐dimensional helical polymer [Ag(PIP)] n ·[Ag(pesd)] n ·2 n H 2 O ( 1 ), which is made up of two independent silver‐containing helical chains, namely [Ag(PIP)] n and [Ag(pesd)] n . There is no direct bonding interaction between the two chains, and the hydrogen bonds between the chains give 1 a two‐dimensional layer supramolecular architecture. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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