Self‐Assembly of Novel Silver Polymers Based on Flexible Sulfonate Ligands | Zendy

Sun Daofeng | Zendy; Cao Rong | Zendy; Bi Wenhua | Zendy; Li Xiaoju | Zendy; Wang Yanqin | Zendy; Hong Maochun | Zendy

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Self‐Assembly of Novel Silver Polymers Based on Flexible Sulfonate Ligands

Author(s) -

Sun Daofeng,

Cao Rong,

Bi Wenhua,

Li Xiaoju,

Wang Yanqin,

Hong Maochun

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300813

Subject(s) - chemistry , sulfonate , dabco , polymer , self assembly , polymer chemistry , stereochemistry , crystallography , organic chemistry , catalysis , sodium

Self‐assembly reactions of sulfonates with AgNO 3 in the presence of secondary N‐ or P‐containing ligands result in the formation of four new silver‐sulfonate polymers, [Ag(PIP)] n ·[Ag(pesp)] n ·2 n H 2 O ( 1 ), [Ag 2 (pesp)(dabco)] n ·5 n H 2 O ( 2 ), [{Ag(pesp) 1/2 (hmt) 1/4 }·0.5H 2 O] n ( 3 ) and [Ag(PPh 3 )(pesp) 1/2 ] n · n MeOH ( 4 ), whose structures change from one‐dimensional chains to three‐dimensional open frameworks based on the secondary ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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