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Self‐Assembly of Novel Silver Polymers Based on Flexible Sulfonate Ligands
Author(s) -
Sun Daofeng,
Cao Rong,
Bi Wenhua,
Li Xiaoju,
Wang Yanqin,
Hong Maochun
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300813
Subject(s) - chemistry , sulfonate , dabco , polymer , self assembly , polymer chemistry , stereochemistry , crystallography , organic chemistry , catalysis , sodium
Self‐assembly reactions of sulfonates with AgNO 3 in the presence of secondary N‐ or P‐containing ligands result in the formation of four new silver‐sulfonate polymers, [Ag(PIP)] n ·[Ag(pesp)] n ·2 n H 2 O ( 1 ), [Ag 2 (pesp)(dabco)] n ·5 n H 2 O ( 2 ), [{Ag(pesp) 1/2 (hmt) 1/4 }·0.5H 2 O] n ( 3 ) and [Ag(PPh 3 )(pesp) 1/2 ] n · n MeOH ( 4 ), whose structures change from one‐dimensional chains to three‐dimensional open frameworks based on the secondary ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)