Structural and Theoretical Studies of New Ruthenium‐Amidato Complexes with Phenanthroline Ligands Containing H‐Bonding Groups | Zendy

Rais Daniela | Zendy; Gould Ian R. | Zendy; Vilar Ramón | Zendy; White Andrew J. P. | Zendy; Williams David J. | Zendy

Premium

Structural and Theoretical Studies of New Ruthenium‐Amidato Complexes with Phenanthroline Ligands Containing H‐Bonding Groups

Author(s) -

Rais Daniela,

Gould Ian R.,

Vilar Ramón,

White Andrew J. P.,

Williams David J.

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300809

Subject(s) - chemistry , ruthenium , supramolecular chemistry , phenanthroline , stacking , deprotonation , ligand (biochemistry) , hydrogen bond , coordination complex , molecule , stereochemistry , crystallography , combinatorial chemistry , catalysis , metal , organic chemistry , ion , biochemistry , receptor

The syntheses, characterization and coordination chemistry of two new 1,10‐phenanthroline‐based ligands are presented here. Crystallographic studies have shown that both molecules display hydrogen‐bonding and π−π stacking interactions, generating interesting supramolecular assemblies in the solid state. The reactions of these ligands with [RuCl 2 (PPh 3 ) 3 ] have been performed and two new ruthenium‐amidato complexes have been prepared. In both cases, the presence of a pyridyl group in the ligand backbone favours the deprotonation of one of the carboxyamido moieties leading to a tridentate coordination mode of the ligands. The structural characterization of one of the ruthenium complexes is also reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research