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Syntheses, Structures and Redox Properties of New Macrocyclic Triazatriolefinic Pd 0 Complexes and Their Polypyrrole Modified Electrodes − Application to Heterogeneous Catalytic Suzuki Cross‐Coupling Reactions
Author(s) -
Llobet Antoni,
Masllorens Ester,
Rodríguez Montserrat,
Roglans Anna,
BenetBuchholz Jordi
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300724
Subject(s) - chemistry , phenylboronic acid , redox , suzuki reaction , catalysis , bromide , polymerization , coupling reaction , aryl , polymer chemistry , pyrrole , combinatorial chemistry , boronic acid , benzyl bromide , palladium , organic chemistry , polymer , alkyl
New triolefinic macrocyclic ligands of the type ( E , E,E )‐1,6,11‐tris(arenesulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐triene (aryl: a = ferrocenyl, b = 4‐pyrrol‐1‐ylphenyl, c = 4‐methylphenyl) and their Pd 0 complexes ( 1aab , 1abb and 1bcc ) have been prepared and characterized. Further structural characterization in the solid state has also been performed by means of X‐ray diffraction analysis for the complex 1bcc . The redox properties of both the ligands and their Pd complexes have been studied using cyclic voltammetric and coulombimetric techniques. In particular, complexes and ligands containing the pyrrole group do polymerize upon exposure to sufficiently positive potentials, on glassy carbon electrodes, generating highly stable modified electrodes. The new modified electrodes are efficient and selective heterogeneous catalysts for Suzuki cross‐couplings, benefiting from simple removal of the catalyst from the reaction vessel. As an example, more than 2·10 5 metal cycles are achieved at 65 °C in the coupling of phenylboronic acid and cinnamyl bromide. Iodoarenes and phenylboronic acid are also converted into biphenyls with relatively good conversions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)