A Blue Photoluminescent 2‐D Coordination Polymer Constructed by Dinuclear Zinc( II ) Subunits [Zn 2 (oz) 2 ] [Hoz = 2‐(2′‐Hydroxyphenyl)‐2‐oxazoline] and Dicyanamide | Zendy

Zhang Jing | Zendy; Gao Song | Zendy; Che ChiMing | Zendy

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A Blue Photoluminescent 2‐D Coordination Polymer Constructed by Dinuclear Zinc( II ) Subunits [Zn 2 (oz) 2 ] [Hoz = 2‐(2′‐Hydroxyphenyl)‐2‐oxazoline] and Dicyanamide

Author(s) -

Zhang Jing,

Gao Song,

Che ChiMing

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300719

Subject(s) - dicyanamide , chemistry , photoluminescence , zinc , thermal stability , oxazoline , polymer , coordination complex , stereochemistry , polymer chemistry , crystallography , medicinal chemistry , organic chemistry , catalysis , ionic liquid , metal , physics , optics

Substitution of the terminal oz group of the dinuclear [Zn(oz) 2 ] 2 complex ( 1 ) with dicyanamide [where Hoz = 2‐(2′‐Hydroxyphenyl)‐2‐oxazoline] results in the formation of a 2‐D coordination polymer [Zn(oz)N(CN) 2 ] n ( 2 ) based on [Zn 2 (oz) 2 ] subunits. Both compounds exhibit strong blue photoluminescence but the coordination polymer 2 has greater thermal stability than the dinuclear complex 1 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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