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Stoichiometric Control of the Magnetic Properties in Copper( II ) Cyano‐Bridged Bimetallic Complexes
Author(s) -
Coronado Eugenio,
GiménezSaiz Carlos,
Nuez Alicia,
Sánchez Víctor,
Romero Francisco M.
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300641
Subject(s) - chemistry , bimetallic strip , copper , stoichiometry , ferromagnetism , crystallography , ion , inorganic chemistry , organic chemistry , catalysis , condensed matter physics , physics
Control of the Cu 2+ ion coordination environment affords a 1D, magnetically diluted compound, [Cu( cis ‐chxn) 2 ] 3 [Fe(CN) 6 ] 2 ·7H 2 O ( 1 ) and the 2D ferromagnetic material [Cu( cis ‐chxn)] 3 [Fe(CN) 6 ] 2 ·6H 2 O ( 2 ) with a critical temperature, T c , of 3.5 K. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)